You need the front rad top bleed screw open with it running, n heater on - it's at a higher level than the rear expansion tank.... Start with that .....
You can also use abit of straight sink white waste pipe - 3ft length or as high as ye can get inside the rear of the van to fill n maybe the sinks bottom threaded white ring, or an old expansion cap drilled to accept the pvcv pipe- attach that to the header/expansion tank n fill with water - you'll be burping it here n it might take a while n get messy - if you've an assistant monitoring the front rad bleeder n doing that up till no bubbles n a constant flow
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Ye might need to do this a few times but it will get the air burped out since air rises n you are creating a further 'highest water' point with your sink waste pipe attachment to expansion tank....
If there's still air in it, check your front to back plastic pipes - the metal insert rings rot out to branflakes - similarly with the front rad hoses - check the connections....
A lot of folk don't bother with that rear of number plate overflow tank n just cap it off - debates back n forth on that but I'd delete it personally....
Best of luck....